5 publications

5 publications

Artificial Metalloenzyme for Enantioselective Sulfoxidation Based on Vanadyl-Loaded Streptavidin

Ward, T. R.

J. Am. Chem. Soc., 2008, 10.1021/ja8017219


Metal: V
Ligand type: Water
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Genetic
Reaction: Sulfoxidation
Max TON: 27
ee: 93
PDB: ---
Notes: ---

Asymmetric Catalytic Sulfoxidation by a Novel VIV8 Cluster Catalyst in the Presence of Serum Albumin: A Simple and Green Oxidation System

Bian, H.-D.; Huang, F.-P.

RSC Adv., 2016, 10.1039/C6RA08153C


Metal: V
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: 140
ee: 77
PDB: ---
Notes: Screening with different serum albumins.

Enantioselective Sulfoxidation Mediated by Vanadium-Incorporated Phytase: A Hydrolase Acting as a Peroxidase

Sheldon, R. A.

Chem. Commun., 1998, 10.1039/a804702b


Metal: V
Ligand type: Undefined
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: ---
Reaction: Sulfoxidation
Max TON: ~194
ee: 66
PDB: ---
Notes: ---

Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: ---
Reaction: Sulfoxidation
Max TON: 550
ee: 66
PDB: ---
Notes: ---

The Rational Design of Semisynthetic Peroxidases

Sheldon, R. A.

Biotechnol. Bioeng., 2000, 10.1002/(SICI)1097-0290(20000105)67:1<87::AID-BIT10>3.0.CO;2-8


Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: ---
ee: 66
PDB: ---
Notes: Reaction performed in 30% organic co-solvent.

Vanadium-Catalysed Enantioselective Sulfoxidations: Rational Design of Biocatalytic and Biomimetic Systems

Sheldon, R. A.

Top. Catal., 2000, 10.1023/A:1009094619249


Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: ---
ee: 68
PDB: ---
Notes: ---