9 publications

9 publications

An asymmetric catalyst

Akabori, S.; Sakurai, S.

Nature, 1956, 10.1038/178323b0

Asymmetric synthesis has hitherto succeeded only by using reagents or solvents having the asymmetric configuration.


Metal: Pd
Ligand type: Undefined
Host protein: Silk fibroin fibre
Anchoring strategy: Undefined
Optimization: ---
Reaction: Hydrogenation
Max TON: >22
ee: ---
PDB: ---
Notes: ---

An Enantioselective Artificial Suzukiase Based on the Biotin–Streptavidin Technology

Ward, T. R.

Chem. Sci., 2015, 10.1039/c5sc03116h


Metal: Pd
Ligand type: Allyl; Phosphine
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Max TON: 88
ee: 80
PDB: ---
Notes: ---

Metal: Pd
Ligand type: Allyl; Carbene
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Max TON: 5
ee: ---
PDB: ---
Notes: ---

Artificial Metalloenzymes for Asymmetric Allylic Alkylation on the Basis of the Biotin–Avidin Technology

Ward, T. R.

Angew. Chem., Int. Ed., 2008, 10.1002/anie.200703159


Metal: Pd
Ligand type: Phosphine
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Reaction: Allylic alkylation
Max TON: 10
ee: 93
PDB: ---
Notes: ---

Artificial Metalloenzymes Through Cysteine-Selective Conjugation of Phosphines to Photoactive Yellow Protein

Kamer, P. C. J.

ChemBioChem, 2010, 10.1002/cbic.201000159


Metal: Pd
Ligand type: Allyl; Phosphine
Anchoring strategy: Covalent
Optimization: Chemical & genetic
Reaction: Allylic amination
Max TON: 45
ee: ---
PDB: 2PHY
Notes: ---

Control of the Coordination Structure of Organometallic Palladium Complexes in an Apo-Ferritin Cage

Ueno, T.; Watanabe, Y.

J. Am. Chem. Soc., 2008, 10.1021/ja802463a


Metal: Pd
Ligand type: Allyl
Host protein: Ferritin
Anchoring strategy: Dative
Optimization: ---
Reaction: Suzuki coupling
Max TON: ---
ee: ---
PDB: 2ZG7
Notes: ---

Definite Coordination Arrangement of Organometallic Palladium Complexes Accumulated on the Designed Interior Surface of Apo-Ferritin

Ueno, T.

Chem. Commun., 2011, 10.1039/C0CC02221G


Metal: Pd
Ligand type: Allyl
Host protein: Ferritin
Anchoring strategy: Dative
Optimization: Genetic
Reaction: Suzuki coupling
Max TON: ---
ee: ---
PDB: ---
Notes: ---

Immobilization of Two Organometallic Complexes into a Single Cage to Construct Protein-Based Microcompartment

Ueno, T.

Chem. Commun., 2016, 10.1039/C6CC00679E


Metal: Ir
Ligand type: Amino acid; Cp*
Host protein: Apo-ferritin
Anchoring strategy: Dative
Optimization: Chemical
Reaction: Hydrogenation
Max TON: ~2
ee: 15
PDB: 5E2D
Notes: Tandem reaction (Hydrogenation and Suzuki-Miyaura coupling) to form biphenylethanol from 4-iodoacetophenone and phenylboronic acid. TON and ee are given for the tandem reaction product.

Metal: Pd
Ligand type: Allyl; Amino acid
Host protein: Apo-ferritin
Anchoring strategy: Dative
Optimization: Chemical
Max TON: ~1
ee: 15
PDB: 5E2D
Notes: Tandem reaction (Hydrogenation and Suzuki-Miyaura coupling) to form biphenylethanol from 4-iodoacetophenone and phenylboronic acid.

Preparation of an Immobilized Lipase-Palladium Artificial Metalloenzyme as Catalyst in the Heck Reaction: Role of the Solid Phase

Filice, M.; Palomo, J. M.

Adv. Synth. Catal., 2015, 10.1002/adsc.201500014


Metal: Pd
Anchoring strategy: Covalent
Optimization: Chemical & genetic
Max TON: ~4160
ee: 96
PDB: ---
Notes: ArM is immobilized on Sepabeads.

Supramolecular Anchoring of NCN-Pincer Palladium Complexes into a β-Barrel Protein Host: Molecular-Docking and Reactivity Insights

Salmain, M.; Thorimbert, S.

Eur. J. Inorg. Chem., 2017, 10.1002/ejic.201700365


Metal: Pd
Ligand type: NCN-Pincer (amines)
Host protein: β-lactoglobulin (βLG)
Anchoring strategy: Supramolecular
Optimization: Chemical
Reaction: Aldol condensation
Max TON: 4.9
ee: 0
PDB: ---
Notes: Aldol condensation of methyl isocyanoacetate and benzaldehyde (trans/cis = 38:62)