1 publication
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Enantioselective Sulfoxidation Mediated by Vanadium-Incorporated Phytase: A Hydrolase Acting as a Peroxidase
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Chem. Commun. 1998, 1891-1892, 10.1039/a804702b
Phytase (E.C. 3.1.3.8), which in vivo mediates the hydrolysis of phosphate esters, catalyses the enantioselective oxidation of thioanisole with H2O2, both in the presence and absence of vanadate ion, affording the S-sulfoxide in up to 66% ee at 100% conversion.
Metal: VLigand type: UndefinedHost protein: PhytaseAnchoring strategy: UndefinedOptimization: ---Notes: ---
Notes: ---
