4 publications

4 publications

Enantioselective Sulfoxidation Mediated by Vanadium-Incorporated Phytase: A Hydrolase Acting as a Peroxidase

Sheldon, R. A.

Chem. Commun., 1998, 10.1039/a804702b


Metal: V
Ligand type: Undefined
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: ---
Reaction: Sulfoxidation
Max TON: ~194
ee: 66
PDB: ---
Notes: ---

Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: ---
Reaction: Sulfoxidation
Max TON: 550
ee: 66
PDB: ---
Notes: ---

Metal Substitution in Thermolysin: Catalytic Properties of Tungstate Thermolysin in Sulfoxidation with H2O2

Sheldon, R. A.

Can. J. Chem., 2002, 10.1139/v02-082


Metal: W
Ligand type: Amino acid
Host protein: Thermolysin
Anchoring strategy: Metal substitution
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: ---
ee: ---
PDB: ---
Notes: ---

The Rational Design of Semisynthetic Peroxidases

Sheldon, R. A.

Biotechnol. Bioeng., 2000, 10.1002/(SICI)1097-0290(20000105)67:1<87::AID-BIT10>3.0.CO;2-8


Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: ---
ee: 66
PDB: ---
Notes: Reaction performed in 30% organic co-solvent.

Vanadium-Catalysed Enantioselective Sulfoxidations: Rational Design of Biocatalytic and Biomimetic Systems

Sheldon, R. A.

Top. Catal., 2000, 10.1023/A:1009094619249


Metal: V
Ligand type: Oxide
Host protein: Phytase
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: ---
ee: 68
PDB: ---
Notes: ---