5 publications

5 publications

A Well-Defined Osmium–Cupin Complex: Hyperstable Artificial Osmium Peroxygenase

Fujieda, N.; Itoh, S.

J. Am. Chem. Soc., 2017, 10.1021/jacs.7b00675


Metal: Os
Ligand type: Amino acid
Host protein: TM1459 cupin
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: Dihydroxylation
Max TON: 45
ee: ---
PDB: 5WSE
Notes: Exclusively cis dihydroxylation product obtained

Metal: Os
Ligand type: Amino acid
Host protein: TM1459 cupin
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: Dihydroxylation
Max TON: 45
ee: ---
PDB: 5WSF
Notes: Exclusively cis dihydroxylation product obtained

Optimization of and Mechanistic Considerations for the Enantioselective Dihydroxylation of Styrene Catalyzed by Osmate-Laccase-Poly(2-Methyloxazoline) in Organic Solvents

Tiller, J. C.

ChemCatChem, 2016, 10.1002/cctc.201501083


Metal: Os
Ligand type: Undefined
Host protein: Laccase
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Dihydroxylation
Max TON: 842
ee: > 99
PDB: ---
Notes: ---

OsO4·Streptavidin: A Tunable Hybrid Catalyst for the Enantioselective cis-Dihydroxylation of Olefins

Ward, T. R.

Angew. Chem., Int. Ed., 2011, 10.1002/anie.201103632


Metal: Os
Ligand type: Undefined
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Genetic
Reaction: Dihydroxylation
Max TON: 16
ee: 97
PDB: ---
Notes: ---

Polymer Enzyme Conjugates as Chiral Ligands for Sharpless Dihydroxylation of Alkenes in Organic Solvents

Tiller, J. C.

ChemBioChem, 2015, 10.1002/cbic.201402339


Metal: Os
Ligand type: Amino acid
Host protein: Laccase
Anchoring strategy: Metal substitution
Optimization: Chemical
Reaction: Dihydroxylation
Max TON: 80
ee: 98
PDB: ---
Notes: ---

The Bovine Serum Albumin-2-Phenylpropane-1,2-diolatodioxoosmium(VI) Complex as an Enantioselective Catalyst for cis-Hydroxylation of Alkenes

Kokubo, T.; Okano, M.

J. Chem. Soc., Chem. Commun., 1983, 10.1039/C39830000769


Metal: Os
Ligand type: Undefined
Anchoring strategy: Undefined
Optimization: ---
Reaction: Dihydroxylation
Max TON: 40
ee: 68
PDB: ---
Notes: ---