Artificial Metalloenzymes Publications @Ward Group

1 publication

Chalcogenide Substitution in the [2Fe] Cluster of [FeFe]-Hydrogenases Conserves High Enzymatic Activity

Combination of biological and chemical methods allow for creation of [FeFe]-hydrogenases with an artificial synthetic cofactor.

Metal: Fe

Ligand type: CN; CO; Diselenolate

Host protein: [FeFe]-hydrogenase from C. pasteurianum (CpI)

Anchoring strategy: Dative

Optimization: Chemical

Reaction: H2 evolution

Max TON: ---

ee: ---

PDB: 5OEF

Notes: ---