1 publication
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An Artificial Metalloenzyme for Carbene Transfer Based on a Biotinylated Dirhodium Anchored Within Streptavidin
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Cat. Sci. Technol. 2018, 8, 2294-2298, 10.1039/C8CY00646F
We report an artificial carbenoid transferase which combines a biotinylated dirhodium moiety within streptavidin scaffold.
Metal: RhLigand type: CarboxylateHost protein: Streptavidin (Sav)Anchoring strategy: SupramolecularOptimization: Chemical & geneticNotes: Cyclopropanation reaction was also performed in the E. coli periplasm.
Metal: RhLigand type: CarboxylateHost protein: Streptavidin (Sav)Anchoring strategy: SupramolecularOptimization: Chemical & geneticNotes: ---
