2 publications

2 publications

Going Beyond Structure: Nickel-Substituted Rubredoxin as a Mechanistic Model for the [NiFe] Hydrogenases

Shafaat, H. S.

J. Am. Chem. Soc., 2018, 10.1021/jacs.8b05194


Metal: Ni
Ligand type: Amino acid
Host protein: Rubredoxin (Rd)
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: H2 evolution
Max TON: ---
ee: ---
PDB: ---
Notes: TOF = 149 s-1

Nickel-Substituted Rubredoxin as a Minimal Enzyme Model for Hydrogenase

Shafaat, H. S.

J. Phys. Chem. Lett., 2015, 10.1021/acs.jpclett.5b01750


Metal: Ni
Ligand type: Tetrathiolate
Host protein: Rubredoxin (Rd)
Anchoring strategy: Metal substitution
Optimization: ---
Reaction: H2 evolution
Max TON: 300
ee: ---
PDB: ---
Notes: ---