3 publications

3 publications

A Protein-Rhodium Complex as an Efficient Catalyst for Two-Phase Olefin Hydroformylation

Marchetti, M.

Tetrahedron Lett., 2000, 10.1016/S0040-4039(00)00473-1


Metal: Rh
Ligand type: Acac; CO2
Anchoring strategy: Undefined
Optimization: ---
Reaction: Hydroformylation
Max TON: ~600
ee: ---
PDB: ---
Notes: ---

Enzyme Activity by Design: An Artificial Rhodium Hydroformylase for Linear Aldehydes

Jarvis, A. G.; Kamer, P. C. J.

Angew. Chem., Int. Ed., 2017, 10.1002/ange.201705753


Metal: Rh
Ligand type: Acac; Diphenylphosphine
Anchoring strategy: Cystein-maleimide
Optimization: Chemical & genetic
Reaction: Hydroformylation
Max TON: 409
ee: ---
PDB: ---
Notes: Selectivity for the linear product over the branched product

Regioselective Hydroformylation of Styrene Using Rhodium-Substituted Carbonic Anhydrase

Kazlauskas, R. J.

ChemCatChem, 2010, 10.1002/cctc.201000159


Metal: Rh
Ligand type: Acac; Carbonyl
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: Hydroformylation
Max TON: 298
ee: ---
PDB: 4CAC
Notes: PDB ID 4CAC = Structure of Zn containing hCAII