3 publications

3 publications

Artificial Metalloenzymes as Catalysts for Oxidative Lignin Degradation

Jarvis, A. G.

ACS Sustainable Chem. Eng., 2018, 10.1021/acssuschemeng.8b03568

Metal: Fe
Ligand type: Tris(pyridylmethyl)amine (TPA)
Host protein: Steroid Carrier Protein 2L (SCP 2L)
Anchoring strategy: Cystein-maleimide
Optimization: Chemical & genetic
Reaction: Lignin oxidation
Max TON: 20
ee: ---
PDB: ---
Notes: Reaction performed with a lignin model compound and hydrogen peroxide as oxidizing agent

Catalyst Design in Oxidation Chemistry; from KMnO4 to Artificial Metalloenzymes

Review

Jarvis, A. G.; Kamer, P. C. J.

Bioorg. Med. Chem., 2014, 10.1016/j.bmc.2014.07.002

Notes: ---

Enzyme Activity by Design: An Artificial Rhodium Hydroformylase for Linear Aldehydes

Jarvis, A. G.; Kamer, P. C. J.

Angew. Chem., Int. Ed., 2017, 10.1002/ange.201705753

Metal: Rh
Ligand type: Acac; Diphenylphosphine
Host protein: Steroid Carrier Protein 2L (SCP 2L)
Anchoring strategy: Cystein-maleimide
Optimization: Chemical & genetic
Reaction: Hydroformylation
Max TON: 409
ee: ---
PDB: ---
Notes: Selectivity for the linear product over the branched product

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