14 publications

14 publications

Aqueous Light Driven Hydrogen Production by a Ru–Ferredoxin–Co Biohybrid

Utschig, L. M.

Chem. Commun., 2015, 10.1039/c5cc03006d


Metal: Co
Ligand type: Oxime
Host protein: Ferredoxin (Fd)
Anchoring strategy: Dative
Optimization: ---
Reaction: H2 evolution
Max TON: 210
ee: ---
PDB: ---
Notes: Recalculated TON

Artificial Hydrogenases Based on Cobaloximes and Heme Oxygenase

Artero, V.

ChemPlusChem, 2016, 10.1002/cplu.201600218


Metal: Co
Ligand type: Oxime
Host protein: Heme oxygenase (HO)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Reaction: H2 evolution
Max TON: 15.3
ee: ---
PDB: ---
Notes: ---

Artificial Metalloproteins Containing Co4O4 Cubane Active Sites

Borovik, A. S.; Don Tilley, T.

J. Am. Chem. Soc., 2018, 10.1021/jacs.7b13052


Metal: Co
Ligand type: OAc; Pyridine
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Max TON: ---
ee: ---
PDB: 6AUC
Notes: Co-complex in Sav WT

Metal: Co
Ligand type: OAc; Pyridine
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Max TON: ---
ee: ---
PDB: 6AUE
Notes: Co-complex in Sav S112Y

Bovine Serum Albumin-Cobalt(II) Schiff Base Complex Hybrid: An Efficient Artificial Metalloenzyme for Enantioselective Sulfoxidation using Hydrogen Peroxide

Bian, H.-D.; Liang, H.

Dalton Trans., 2016, 10.1039/C5DT04507J


Metal: Co
Ligand type: Amine; Phenolate
Anchoring strategy: Supramolecular
Optimization: Chemical
Reaction: Sulfoxidation
Max TON: 98
ee: 87
PDB: ---
Notes: ---

Cobaloxime-Based Artificial Hydrogenase

Artero, V.

Inorg. Chem., 2014, 10.1021/ic501014c


Metal: Co
Ligand type: Oxime
Host protein: Myoglobin (Mb)
Anchoring strategy: Supramolecular
Optimization: Chemical
Reaction: H2 evolution
Max TON: 5
ee: ---
PDB: ---
Notes: Sperm whale myoglobin

Metal Incorporated Horseradish Peroxidase (HRP) Catalyzed Oxidation of Resveratrol: Selective Dimerization or Decomposition

Pan, Y.

RSC Adv., 2013, 10.1039/c3ra43784a


Metal: Ca; Co; Mn; Ni; Zn
Ligand type: Undefined
Anchoring strategy: Undefined
Optimization: Chemical
Reaction: Oxidation
Max TON: ---
ee: ---
PDB: ---
Notes: Oxidation of resveratrol. Dimerisation product obtained.

Metal Ion Dependent Binding of Sulphonamide to Carbonic Anhydrase

Coleman, J. E.

Nature, 1967, 10.1038/214193a0


Metal: Co
Ligand type: Amino acid
Host protein: Human carbonic anhydrase
Anchoring strategy: Metal substitution
Optimization: ---
Max TON: ---
ee: ---
PDB: ---
Notes: CO2 hydration

Metal: Co
Ligand type: Amino acid
Host protein: Human carbonic anhydrase
Anchoring strategy: Metal substitution
Optimization: ---
Max TON: ---
ee: ---
PDB: ---
Notes: Ester cleavage

Nature-Driven Photochemistry for Catalytic Solar Hydrogen Production: A Photosystem I-Transition Metal Catalyst Hybrid

Tiede, D. M.; Utschig, L. M.

J. Am. Chem. Soc., 2011, 10.1021/ja206012r


Metal: Co
Ligand type: Oxime; Pyridine
Host protein: Photosystem I (PSI)
Anchoring strategy: Undefined
Optimization: ---
Reaction: H2 evolution
Max TON: 2080
ee: ---
PDB: ---
Notes: Recalculated TON

Photo-Driven Hydrogen Evolution by an Artificial Hydrogenase Utilizing the Biotin-Streptavidin Technology

Alberto, R.; Ward, T. R.

Helv. Chim. Acta, 2018, 10.1002/hlca.201800036


Metal: Co
Ligand type: Bipyridine; Pyridine
Host protein: Streptavidin (Sav)
Anchoring strategy: Supramolecular
Optimization: Chemical & genetic
Reaction: H2 evolution
Max TON: >1800
ee: ---
PDB: 6FRY
Notes: ---

Protein Secondary-Shell Interactions Enhance the Photoinduced Hydrogen Production of Cobalt Protoporphyrin IX

Ghirlanda, G.

Chem. Commun., 2014, 10.1039/c4cc06700b


Metal: Co
Ligand type: Porphyrin
Host protein: Myoglobin (Mb)
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: H2 evolution
Max TON: 518
ee: ---
PDB: ---
Notes: ---

Reengineering Cyt b562 for Hydrogen Production: A Facile Route to Artificial Hydrogenases

Ghirlanda, G.

Biochim. Biophys. Acta, Bioenerg., 2016, 10.1016/j.bbabio.2015.09.001


Metal: Co
Ligand type: Porphyrin
Host protein: Cytochrome b562
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: H2 evolution
Max TON: 1450
ee: ---
PDB: ---
Notes: ---

Ru–protein–Co Biohybrids Designed for Solar Hydrogen Production: Understanding Electron Transfer Pathways Related to Photocatalytic Function

Utschig, L. M.

Chem. Sci., 2016, 10.1039/c6sc03121h


Metal: Co
Ligand type: Oxime
Host protein: Ferredoxin (Fd)
Anchoring strategy: Dative
Optimization: Chemical
Reaction: H2 evolution
Max TON: 650
ee: ---
PDB: ---
Notes: Recalculated TON

Semisynthetic and Biomolecular Hydrogen Evolution Catalysts

Bren, K. L.

Inorg. Chem., 2016, 10.1021/acs.inorgchem.5b02054


Metal: Co
Ligand type: Porphyrin
Host protein: Cytochrome c552
Anchoring strategy: Metal substitution
Optimization: Genetic
Reaction: H2 evolution
Max TON: 27000
ee: ---
PDB: ---
Notes: Electrocatalysis

Stereoselective Sulfoxidation Catalyzed by Achiral Schiff Base Complexes in the Presence of Serum Albumin in Aqueous Media

Bian, H.-D.; Huang, F.-P.

Tetrahedron: Asymmetry, 2017, 10.1016/j.tetasy.2017.10.021


Metal: Co
Anchoring strategy: Undefined
Optimization: ---
Reaction: Sulfoxidation
Max TON: ~60
ee: 59
PDB: ---
Notes: ---