Artificial metalloenzymes publications - Ward Group - Department of Chemistry

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3 publications

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Artificial Metalloproteins Containing Co4O4 Cubane Active Sites

Borovik, A. S.; Don Tilley, T.

J. Am. Chem. Soc., 2018, 10.1021/jacs.7b13052

Metal:

Ligand type:

OAc; Pyridine

Host protein:

Streptavidin (Sav)

Anchoring strategy:

Supramolecular

Optimization:

Chemical & genetic

Reaction:

Electron/Proton transfer

Max TON:

---

ee:

---

PDB:

6AUC

Notes:

Co-complex in Sav WT

Metal:

Ligand type:

OAc; Pyridine

Host protein:

Streptavidin (Sav)

Anchoring strategy:

Supramolecular

Optimization:

Chemical & genetic

Reaction:

Electron/Proton transfer

Max TON:

---

ee:

---

PDB:

6AUC

Notes:

Co-complex in Sav S112Y

Artificial Metalloproteins Containing Co4O4 Cubane Active Sites

Borovik, A. S.; Don Tilley, T.

J. Am. Chem. Soc., 2018, 10.1021/jacs.7b13052

Metal:

Ligand type:

OAc; Pyridine

Host protein:

Streptavidin (Sav)

Anchoring strategy:

Supramolecular

Optimization:

Chemical & genetic

Reaction:

Electron/Proton transfer

Max TON:

---

ee:

---

PDB:

6AUC

Notes:

Co-complex in Sav WT

Metal:

Ligand type:

OAc; Pyridine

Host protein:

Streptavidin (Sav)

Anchoring strategy:

Supramolecular

Optimization:

Chemical & genetic

Reaction:

Electron/Proton transfer

Max TON:

---

ee:

---

PDB:

6AUC

Notes:

Co-complex in Sav S112Y

Peroxide Activation Regulated by Hydrogen Bonds within Artificial Cu Proteins

Borovik, A. S.

J. Am. Chem. Soc., 2017, 10.1021/jacs.7b10452

Metal:

Ligand type:

Bis(2-(pyridin-2-yl)ethyl)amine

Host protein:

Streptavidin (Sav)

Anchoring strategy:

Supramolecular

Optimization:

Chemical & genetic

Reaction:

Oxidation

Max TON:

---

ee:

---

PDB:

6ANX

Notes:

---