1 publication

1 publication

Orthogonal Expression of an Artificial Metalloenzyme for Abiotic Catalysis

Brustad, E. M.

ChemBioChem, 2017, 10.1002/cbic.201700397


Metal: Ir
Ligand type: Methyl; Porphyrin
Host protein: Cytochrome BM3h
Anchoring strategy: Reconstitution
Optimization: Chemical & genetic
Reaction: Cyclopropanation
Max TON: 339
ee: 97
PDB: ---
Notes: Reaction of styrene with ethyl diazoacetate, cis:trans = 29:71